Chemically curable liquid polyene-polythiol polymer composition

ABSTRACT

The invention disclosed is for a new chemically curable liquid polymer composition which includes a liquid polyene component having a molecule containing at least two unsaturated carbon-tocarbon bonds disposed at terminal positions on a main chain backbone of the molecule, and a polythiol component having a molecule containing a multiplicity of pendant or terminally positioned -SH functional groups per average molecule. The chemically curable liquid polymer composition upon curing in the presence of a chemical free radical generating reagent forms odorless, solid, elastomeric products which may serve as sealants, coatings, adhesives, and molded articles.

United States Patent Kehr et al. 1 Oct. 10, 1972 I 541 CHEMICALLY CURABLE LIQUID [56] References Cited POLYENE-POLYTHIOL POLYMER 7 I COMPOSITION ED STATES PATENTS [72] Inventors: Clifton L. Kelli, Silver spring; 3,405,181 10/1968 Gourdon ....,...,.....,......260/79 wsmlek sykesville Md. El'lckson 3,371,072 2/1968 sigl'loul'tet t 3.1.. ..260/79 Assignee: Grace & New 3,338,810 8/1967 260/79 N.Y. 3,412,049 11/1968 Gmitter... ..260/2.5 R [22] Filed: I June 25 1971 2,921,006 1/1960 Schmitz etal. ..;....204/159.15

[21] Appl. No.: 156,967 Primary Examiner-Murray Tillman t 1 Assistant Examiner-Richard B. Turer Related Apphcauon Dam Attorney-Eugene M. Bond et al. [60] Division Of Ser. NO. 49,207, June 23, 1970,

Pat. No. 3,662,023, which is a continuation-in- ABSTRACT 1 pan of Q' P- 1967' aban' The invention disclosed is for a new chemically curawh'ch a commuauon'm'part of ble liquid polymer composition which includes a liquid 567,841 X 1966' abandoned polyene component having a molecule containing at least two unsaturated carbon-to-carbon bonds [52] US. Cl. ..260/858, 117/93.31,'117/ 132 B, disposed at terminal positions on a main chain 117/132 R, 117/138-8 117/148 117/155 backbone of the molecule, and a polythiol component 204/ 15914 204/ 15915 204/ having a molecule containing a multiplicity of pendant 204/159-23, 204/5914 260/25 260/25 or terminally positioned SH functional groups per R, 0 R, 1 260/41 Br26O/41R. average molecule. The chemically curable liquid [51 Int. Cl ..C08d 1/00, C08f 1/ 16, C086 1 l/54 polymer composition upon curing i h presence f a Field of 79-7, chemical free radical generating reagent forms odor- 260/79.5 B, 79.5 R, 79.5 CR, 858; 204/l59.l8, 159.23, 159.14

' 14 Claims, No Drawings CHEMICALLY CURABLE LIQUID POLYENE- POLYTHIOL POLYMER COMPOSITION The present application for U.S.'Letters Patent is a divisional of Ser. No. 49,207, filed June 23, 1970, now U.S. Pat. No. 3,662,023,-issued on May 9, 1972 which in turn is a continuation-impart of copending application Ser. No. 617,801, filed Feb. 23, 1967, now abandoned, which in turn'is a continuation-in-part of application Ser. No. 567,841,- filed July 26, 1966, now abandoned.

Thisinvention relates to a new high energy curable liquid composition which includes a liquid polyene componenthaving a molecule containing at least two unsaturated carbon-to-carbon bonds disposed at terminal positions on a main chain of the molecule, a polythiol component having a molecule containing a multiplicity of pendant or terminally positioned SH functional groups per average molecule, and a photo curing rate accelerator.

It is well known in the art that cure of internally unsaturated polymers such as polybutadiene or polyisoprene may be effected with polythiols. However, such polymers, due mainly to residual internal unsaturation after curing, are unstable either to thermal oxidation or ultra-violet catalyzed oxidation, and are subject to rapid attack by ozone. Eventually degradation and embrittlement results in the internal double bond polymers, substantially reducing their useful service life.

A limitation of commercially available liquid polyu rethane prepolymers is the fact that they are terminated by isocyanate (--NCO) groups. These NCO groups are extremely unstable in storage, and are highly water-sensitive such that under practical conditions, they react with traces of moisture from the atmosphere to form gaseous carbon dioxide and amino groupings which in turn react with more NCO to form eventually a highly viscous, sometimes cornpletely insoluble urea-extended chain network. In cases'where insolubilization occurs, the polymer has to be discarded at great expense. Further, if the -NCO-terminated prepolymers come in contact with traces of either acidic or basic impurities, dimerization and/or trimerization of the -NCO functions may take place .to form viscous, sometimes insoluble products during storage. Even mild alkalis such as those constituents normally present on the surface of glass vessels and containers may cause storage problems. i

A further limitation for some applications is found in polyurethane polymers of the prior art which are derived from aromatic diisocyanates or polyisocyanates such as tolylene-2,4-diisocyanate, tolylene- 2,6-diisocyanate, 4,4-diisocyanatodiphenylmethane, and the like. These aromatic diisocyanates (or mixtures thereof) enjoy widespread use in polyurethane elastomers, foams, and coatings, because of their ready commercial availability, high degree of reactivity and relatively low cost. The derived polyurethane products, however, are known to turn yellow, amber, orange or brown in color when exposed to sunlight, ultraviolet light or other forms of actinic radiation. This yellowing tendency imparts a definite limitation on the usage of such polyurethanes in many applications. There is evidence in the technical literature that shows that this yellowing or discoloration problem is directly attributacoupling of the thiol (--Sl-l) groups to disulfides (-S' S-groups) are known in the sealants, coatings and adhesives field. Oxidizing agents such as PbO: are commonly used to effect this curing reaction. These mercapto-containing compounds, however, both before and after curing with Pb0 -type curing system yield elastomeric compositions with an offensive odor which limits their usefulness generally to outdoor service. Thus, oxidatively cured mercapto polymer systems have found restricted commercial acceptance due to their offensive odors.

A limitation of commercial liquid polymeric sealants and coatings is found in one-package systems. All the compounding ingredients, including the curing agents, are blended together and charged into a tightly sealed container until used. In these commercial sealants (polysulfides, polydisulfides, polymercaptans, polyurethanes and polysilicones), the curing reaction of onepackage systems is initiated by moisture (H 0) from the air. The moisture-curable systems leave something to be desired because the moisture content of the air varies widely. Hence, the curing performance of moisturecurable adhesives, coatings and sealants is variable and is difficult to predict and control. ln the case of polyurethanes a further disadvantage of moisture-curable systems is observed. In the curing reaction (NCO groups reacting with H 0) a volatile gas (carbon dioxide) is liberated and this evolved gas tends to cause unsightly and property-weakening gas pockets or voids in the final product.

It has now been found that numerous defects of the prior art may be effectively overcome by practice of the present invention which provides a new chemically curable liquid composition which contains particular polyenes which are curable with polythiols to solid resins or elastomers. For example, when urethane-containing polyenes are compounded with polythiols, the prepared composition may be stored safely for long periods of time in the absence of a chemical free radical generating reagent. Upon exposure to a chemical free radical generating reagent, the system cures rapidly and controllably to a polythioether-polyurethane product which is low in cost and equal or better in reaction rate in polymer formation when compared with compositions derived from conventional technolo- Generally stated, the present invention provides a curable composition which comprises a particular polyene component, a polythiol component, and a chemical free radical generating reagent.

The polyene component may be represented by the formula:

carbon atoms.

3 [fifth wherein m is aninteger of at least 2, wherein is a member selected from the group consisting of:

in the groups (a) to (e), f is an integer from 1 to 9; R

is a radical selected from the group consisting of hydrogen, fluorine, chlorine, furyl, thienyl, .pyridyl,

phenyl and substituted phenyl, benzyl and substituted benzyl, alkyl and substituted alkyl, alkoxy and substituted alkoxy, and cycloalkyl and substituted cycloalkyl. The substituents on the substituted members are selected froin' 1the group consisting of nitro, chloro,

fluoro, acetoxy, acetamide, phenyl, benzyl, alkyl, alkoxy and cycloalkyl. Alkyl and alkoxy have from .1 to 9 carbon atoms and cycloalkyl has from three to eight The members (a). to (e) are connected to [A] through divalent. chemically compatible derivative members. The members (a) to (e) may be connected to [A] through a divalent chemically compatible derivative member of the group consisting of Si(R),, carbonate, carboxylate, sulfone, --0-, v

alkyl and substituted ,alkyl, cycloalkyl and substituted eycloalkyl, urethane and substituted urethane, urea and substituted urea, amide and substituted amide, amine'and substituted amine, and aryl and substituted aryl. The alkyl members have from one to nine carbon atoms, the aryl members are either phenyl or naphthyl, and the cycloalkyl members have from three to eight carbon atoms with Rand said members substituted being defined above. B is a member of the group consisting 0, S-, and NR.

essentially 0 to 20 million centipoises'at C. as measured by a Brookfield viscometer.

The polythiol component has a molecular weight'in the range from about 50 to about 20,000 and th general formula:

wherein R is apolyvalent organic moiety free from reactive carbon-torcarbon unsaturation and rt isat least 2. The ene/thiol mole ratio'is selectedso as to provide a solid, self-supporting cured product. under ambient conditions in the presence of a free radical generator.

More particularly, the member [A] of the polyene composition may be formed primarily of alkyl radicals,

phenyl and urethane derivatives, oxygenated,radicals,

and nitrogen substituted radicals. The member [A] may also be represented by the formula:

Betcha mi, M 1,

wherein j and k are integers greater than 1; R, is a member of the group consistin'gof hydrogen, and alkyl having one to nine carbon atoms; R, is a member of the group consisting of hydrogen, and saturated alkyl having one to nine carbon atoms; R, is a divalent derivative of the group consisting of phenyl, benzyl, alkyl, cycloal-- kyl, substituted phenyl, substituted benzyl, substituted alkylaand substituted cycloalkyl; with the terms alkyl,

cycloalkyl and members substituted being defined above.

General representative formulasfor the polyenes of the present invention may be prepared as exemplified below:

I Poly (alkylene-ether) Polyol Reacted with Unsaturated Monoisocyanates Forming Polyurethane Polyenes and Related Polymers Diiuuetional Tetrat'unctional f he. P P essist ns 2? CBA C HL .1] hydrogen, phenyl ,-cycloalkyl, and alkyl M The novel classof polyenes of this invention derived from carbon to carbon unsaturated monoisocyanates may be characterized by extreme ease and versatility of manufacture when the liquid functionality desired is greater than about three. For example, consider an attempted synthesis of a polyhexene starting with an OH terminated polyalkylene ether hexol suchas Niax l-lexol LS-490 (Union Carbide Corp.) havinga molecular weight of approximately 700, and a viscosity of 18,720 cps atI C. An attempt to terminate this polymer with ene groups by reacting one mole of hexol with 6 moles of tolylene diisocyanate.(mixed 2,4, 2 6isomer.product) and 6 moles of allyl alcohol proceeded nicely but resulted in a prematurely chain extended vand crosslinked solid product rather than an intended liquid polyhexene. Using the monoisocyanate route, however, this premature chain extension may be avoided and the desired polyurethane-containing liquid polyhexe'nemayfbe very easily prepared by a simple,

0 Clairol NH I on,

H=CHr 4 amine or yne-amine is addedto the NCO terminated polymer formed. The'group consisting of ene-ol, yne-.v

.ol, ene-amine and yne-amineare usually added to the reaction in an amount such that there is one carbon-tocarbon unsaturation in the group member per hydroxyl group in the polyol and said polyol and group member are added in combination in a stoichiometric amount necessary to'react with the isocyanate groups in. the polyisocyanate. v l

A second general method of forming a polyene containing urethane groups (or urea groups) is to react a polyol (or polyamine) with an ene-isocyanate or an yne-isocyanate to form the corresponding polyene. The

general procedure and stoichiometry of this synthesis routeis similar to that described for polyisocyanates in the preceding, In this instance, a polyol reacts with an cue-isocyanate to form the corresponding polyene. it is I found, however, that products derived from this route,

one-step reaction of one: mole of he'xol withr6 moles of allyl isocyanate. This latter polyhexene has the added advantage of being cured using the teachings of this in-, vention to a non-yellowing polythioether polyurethane product. Similarly, the unsaturated monoisocyanate technique may be usedto prepare liquid polyenes from other analagous highly functional polyo'ls such as cellulose, polyvinyl alcohol, partially hydrolized polyvinyl acetate, and the like, and highly functional polyamines such as tetraethylene pentamine, polyethyleneimine, and the like. i I

A general method of forming. one type of polyene containing urethane groups is to react a polyol of the general formula R 4 OH), wherein R is a polyvalent organic moiety free from reactive carbon-to-carbon unsaturation and n is at least 2; with a polyisocyanate of the general formula R1z (NCO). wherein R is a polyvalent organic moiety free from reactive carbonto-carbon unsaturation and n is at least 2 and a member i of the group consisting of an ene-ol, yne-ol, ene-amine and yne-amine. The reaction is carried out in, an inert moisture-free atmosphere (nitrogen blanket) at at mospheric pressure at a temperature in the range from- 0 to about 120 C for a period of above 5 minutesto about 25 hours. In the case where an ene-ol or yne-ol is employed, the reaction is preferably a one step reaction.

wherein all the'reactants are charged together. In the when cured in the presence of a chemical. free radical generating reagent and a polythiol, may form relatively weak'solid polythioether products. To obtain stronger cured products, it is desirable to provide polar functional groupings within the main chain backbone of the polymeric polyene. These polar-functional groupings serve as connecting linkages between multiple repeating units in the main chain series, and serve as internal strength-reinforcing agents by virtue of their ability to 'create strong interchain attraction forces between molecules of polymer in the final cured composition.

Polyenes containing ester groups may be formed'by reacting an acid of the formula R fCOol-l), wherein R is a polyvalent organic moiety free from reactive carbon-to-carbon unsaturation and n is at least 2; with either an ene-ol or yne-ol. The reaction is carried out in an inert moisture-free atmosphere (nitrogen blanket) at atmospheric pressure at a temperature in the range from 0 to about C. for a period of 5'minutes to 25 hours. Usually the reaction is carried out in. the presence of a catalyst (p-toluene sulfonic acid) and in the presence of a solvent,e.g. benzene at refluxing tem-. perature. The water formed is azeotroped off of the reaction.

Another method of making an ester containing polyene is to react a polyol of the formula R 4 0H),,

I is carried out in the same manner as set out above for the ester-containing polyenes. In practicing this latter technique, however, it may be found that ene-acids (or yne-acids) in which the em (or yne) group is adjacent to an activating polar moiety such as O O A t an, 4

vinyl polymers. Excessive amounts of self-polymerization of the ene groups is an undesirable side reaction in the present invention since the desired polythioether reaction products are precluded whenever selfpolymerization of the cue groups occurs. Finally, the presence of activated, easily self-polymerizable ene groups in the composition leads to oxygen inhibition during curing, storage stability problems, or the need for excessively high inhibitor concentrations.

In forming the urethane-containing polyenes of the present invention, catalytic amounts of a catalyst may be employed to speed up the reaction. This is especially true in the case where an ene-ol is used to form the polyene. Such catalysts are well known to those in the art and include organometallic compounds such as stannous octoate, stannous oleate, dibutyl tin dilaurate, cobalt acetylacetonate, ferric acetylacetonate, lead naphthanate and dibutyl tin diacetate.

In summary, by admixing polyenes or polyynes containing two or more reactive unsaturated carbon-tocarbon bonds located terminal from the main chain with a polythiol containing two or more thiol groups per molecule and thereafter exposing said liquid mixture to a chemical free radical generating reagent, there is provided an essentially odorless solid elastomeric or resinous polymeric product.

Polythiol as used herein refers to simple or complex organic compounds having a multiplicity of pendant or terminally positioned SH functional groups per average molecule.

On the average the polythiol must contain 2 or more SH groups/molecule and have a viscosity range of essentially to million centipoises (cps) at 70 C as measured by a Brookfield Viscometer either alone or when in the presence of an inert solvent, aqueous dispersion or plasticizer. Operable polythiols in the instant invention usually have molecular weights in the range about 50 to about 20,000 and preferably from about 100 to about 10,000.

The polythiols operable in the instant invention may be exemplified by the general formula R8-("SH),

where n is at least 2 and R8 is a polyvalent organic moiety free from reactive carbon-to-carbon unsaturation. Thus R8 may contain cyclic groupings and hetero atoms such as N, P or O and primarily contains carbon-carbon, carbon-hydrogen, carbon-oxygen, or silicon-oxygen containing chain linkagesfree of any reactive carbon-to-carbon unsaturation.

One class of polythiols operable with polyenes to obtain essentially odorless polythioether products are esters of thiol-containing acids of the formula HS-- R COOH where R is an organic moiety containing no reactive carbon-to-carbon unsaturation with polyhydroxy compounds of structure R (O H) where where R and R are organic moieties containing no reactive carbon-to-carbon unsaturation, and n is 2 or greater.

16) Certain polythiols such as the aliphatic monomeric polythiols (ethane dithiol, hexamethylene dithiol,

decamethylene dithiol, tolylene-2,4-dithiol, and the like, and some polymeric polythiols such as a thiol-terminated ethylcyclohexyl dimercaptan polymer, and the like, and similar polythiols which are conveniently and ordinarily synthesized on a commercial basis, although taerythritol tetrakis (thioglycolate) and pentaerythritol tetrakis (B-mercaptopropionate), all of which are commercially available. A specific example of a preferred polymeric polythiol is polypropylene ether glycol bis (B-mercaptopropionate) which is prepared from polypropylene-ether glycol e.g. Pluracol P2010, Wyandotte Chemical Corp.) and B-mercaptopropionic acid by esterification.

The preferred polythiol compounds are characterized by a low level of mercaptan-like odor initially, and after reaction, give essentially odorless polythioether end products which are-commercially attractive and practically useful resins or elastomers for both indoor and outdoor applications.

Prior to curing, the curable liquid polymer may be formulated for use as percent solids, or disposed in organic solvents, or as dispersions or emulsions in aqueous media.

The curable liquid polymer compositions prior to curing may readily be pumped, poured, siphoned, brushed, sprayed, doctored, or otherwise handled as desired. Following application, curing in place to a solid resin or elastomer may be effected either very rapidly or extremely slowly as desired by manipulation of the compounding ingredients and the method of curmg.

The liquid polythioether-forming components and compositions, prior to curing, may be admixed with or blended with other monomeric and polymeric materials such as thermoplastic resins, elastomers or thermosetting resin monomeric or polymeric compositions. The resulting blend may be subjected to conditions for curing or co-curing of the various components of the blend to give cured products having unusual physical properties.

Although the mechanism of the curing reaction is not completely understood, it appears most likely that the curing reaction may be initiated by most any chemical free radical generating reagent which dissociates or abstracts a hydrogen atom from an SH group, or accomplishes the equivalent thereof. Generally the rate of the curing reaction may be increased by increasing the temperature of the composition at the time of initiation of cure. In many applications, however, the curing is accomplished conveniently and economically by .ly to expose the polyene and polythiol admixture to a chemical free radical generating reagent such as oxygen containing gas and obtain a cured solid elastomeric or resinous product.

By proper choice of .type and concentration of chemical free radical generating reagent, the curing period required forconversion of the polyene/polythiol composition from the liquid to the solid state may be varied greatly as desired. In combination with suitable accelerators or retarders, the curing period in the presence of thevarious chemical free radical generating reagents may vary from about a few minutes or less to about'30 days or more. In general, the short curing periods are achieved in applications where thin films of curable composition are required, such as in the field of coatings, whereas the long curing periods are achieved and desired where more massive layers of composition I are required, suchas in the field of elastomeric sealants.

Chemical free radical generating reagents operable in this invention include oxygen; ozone, chlorine; organic peroxides and hydroperoxides; peracids; persulfates; inorganic peroxides; and azo compounds such as azobisisovaleronitrile. Certain of these compounds may be made more effective and efficientif used in conjunction with co-agent curing rate accelerators. Examples of accelerated systems may include benzoyl peroxide with dimethylaniline as an accelerator; cumene hydroperoxide with cobalt naphthenate as an accelerator; and the like. Included in this class are reagents or components which are generated in situ in the composition. Curing periods may be varied, but the reactions are generally relatively fast. Conversions from liquid to solid state may occur within a few minutes.

The chemical free radical generating a reagent is usually added in an amount ranging from about 0.0005 to about 25 percent by weight ofthe photocurable composition, with the preferred range being from about 0.05 to about percent by weight.

Conventional curing inhibitors or retarders which may be used in order to stabilize the components or curable compositions so as to prevent premature onset of curing may include hydroquinone; p-tert.-butyl catechol; 2,6-ditert.-butyl-p-methylphenol; phenothiazine; N-phenyI-Zmaphthylamine; inert gas atmospheres such as helium, argon, nitrogen and carbon dioxide; vacuum; and the like.

To obtain the maximum strength, solvent resistance, creepresistance, heat resistance and freedom from tackiness, the reaction components consisting of the polyenes and polythiols of this invention are formulated in such a manner as to give solid, crosslinked, three dimensional network polythioether polymer systems on curing. In order to achieve such infinite network formation the individual polyenes and polythiols must have a functionality of at least 2 and the sum of the functionalities of the polyene and polythiol components must always be greater than 4. Blends and mixtures of the polyenes and the polythiols containing said functionality are also operable herein.

The compositions to be cured, i.e., (converted to solid resins or elastomers) in accord with the present invention may, if desired, include such additives as antioxidants, accelerators, dyes, inhibitors, activators, fillers, pigments, anti-static agents, flame-retardant agents, thickeners, thixotropic agents, surface-active agents, viscosity modifiers, extending oils, plasticizers, tackifiers and the like within the scope of this invention; Such additives are usually preblended with the polyene or polythiol prior to or during the compounding step. Operable fillers include natural and synthetic resins, carbon black, glass fibers, wood flour, clay, silica, alumina, carbonates, oxides, hydroxides, silicates, glass flakes, glass beads, borates, phosphates, diatomaceous earth, talc, kaolin, barium sulfate, calcium sulfate, calcium carbonate, antimony oxide and the like. The aforesaid additives may be present in quantities up to 500 parts or more per 100 parts polymer by weight and preferably about 0.0005 to about 300 parts on the same basis.

The compounding of the components prior to curing may be carried out in several ways. For example, the polyene, the polythiol and any other inert additives may be admixed in an inert atmosphere and charged to an oxygen-free aerosol can, drum, tube,or cartridgefor subsequent use. Exposure of admixed components to desirably about 0.75/1 to about 1.5/1.

The following examples will aid in explaining, but should not be deemed as limiting, the instant invention. In all cases, unless otherwise noted, all parts and percentages are by weight.

FORMATION oF POLYENE PREPOLYMER EXAMPLE 1 458 g. (0.23 mole) of a commercially available liquid polymeric diisocyanate sold under the' tradename Adiprene L-lOO by E. I. duPont de Nemours & Co.

was charged to a dry resinkettlemaintained under a nitrogen atmosphere and equippedwith a condenser, stirrer, thermometer, and gas inlet and outlet. 37.8 g. (0.65 mole) of allyl alcohol was charged to the kettle and the reaction was continued for 17 hours with stirring at l00 C. Thereafter the nitrogen atmosphere was removed and the kettle was evacuated 8 hours at C. 50 cc. dry benzene was added to the kettle and the reaction product was azeotroped with benzene to remove the unreacted alcohol. This allyl terminated liquid prepolymer had a molecular weight of approximately 2,100 and will be referred to as Prepolymer A hereinafter.

EXAMPLE 2 400 g (0.2 mole) of Adiprene L-l00" was charged to a dry resin kettle maintained under nitrogen and equipped with a condenser, stirrer, thermometer andgas inlet and outlet. 25.2.g.,(0.43 mole) of propargyl al-. cohol (HC ll canon was added to the kettle and the reaction was continued with stirring for 18 hours at C. Thereafter the nitrogen atmosphere was removed and the kettle was evacuated 16 hours at 100C followed. by s sqfirqr s qisti laticns h water and then 50 cc. benzene to remove any excess propargyl alcohol. This HC C terminated liquid prepolymer had a viscosity of 27,500 centipoises at 70 C and a molecular weight of 2,100 and will be referred to as Prepolymer B hereinafter.

EXAMPLE 3 1 mole of commercially available poly(ethylene ether) glycol having a molecular weight of 1,450 and a specific gravity of 1.21 was charged to a resin kettle maintained under nitrogen and equipped with a condenser, stirrer, thermometer and a gas inlet and outlet. 2.9 g. dibutyl tin dilaurate as a catalyst was charged to the kettle along with 2 moles tolylene-2,4-diisocyanate and 2 moles of allyl alcohol. The reaction was continued with stirring at 60 C for 2 hours. Thereafter a vacuum of 1 mm. was applied for 2 hours at 60 C to remove the excess alcohol. This CH =CH terminated prepolymer had a molecular weight of approximately 1950 and will hereinafter be referred to asPrepolymer C.

EXAMPLE 4 1 mole of a commercially available poly(propylene ether) glycol having a molecular weight of about 1,958 and a hydroxyl number of 57.6 was charged to a resin kettle equipped with a condenser, stirrer, thermometer and a gas inlet and outlet. 4 g. of dibutyl tin dilaurate as a catalyst was added to the kettle along with 348 g. (2.0 moles) of tolylene-2,4-diisocyanate and 116 g. (2 moles) of allyl alcohol. The reaction was carried out for 20 minutes at room temperature under nitrogen. Excess alcohol was stripped from the reaction kettle by vacuum over a 1 hour period. The thus formed CH =Cl-lterminated liquid prepolymer had a molecular weight of approximately 2,400 and will hereinafter be referred to as Prepolymer D.

EXAMPLE 5 750 g. of a N-containing tetrol (hydroxyl functionality 4) available from Wyandotte Chemicals Corp. under the tradename Tetronic Polyol 904 having a M.W. of 7,500 was placed in a reaction vessel heated at 1 C. The flask was maintained under vacuum for 1 hour. Then, under an atmosphere of nitrogen, 0.1 cc. dibutyl tin dilaurate was added and the flask was cooled to 50 C. Now 18.3 g. allyl isocyanate was added slowly, maintaining the temperature at about 95 C for about 1 hour after the addition was completed. The thus formed polymeric polyene (i.e., Prepolymer E hereinafter) had a theoretical allyl functionally of 2.2 a theoretical hydroxyl functionality of 1.8, and a calculated molecular weight of about 7,683.

EXAMPLE 6 To a resin kettle maintained under a nitrogen atmosphere and equipped with a condenser, stirrer, thermometer and gas inlet and outlet was added 843 g. of a commercially available liquid diisocyanate prepolymer sold under the tradename Multrathane F-l96 by Mobay Chemical Co., said prepolymer having a molecular weight of about 1680 and an available isocyanate content of 4.7 5.2 percent. 87 g. (1.5 moles) of allyl alcohol was added to the kettle and the reaction was continued for 18 hours at 140 C with stirring. Thereafter the nitrogen atmosphere was removed and the kettle was evacuated for 22 hours at 100 C. 55 cc. of dry benzene was added to the kettle and the reaction product was azeotroped therewith to remove any unreacted alcohol. This CH =CH terminated liquid prepolymer had a viscosity of 25,000 centipoises at C and a molecular weight of approximately 1,800 and will be referred to as Prepolymer F hereinafter.

EXAMPLE 7 i 678 g. (0.34 moles) of a commercially available poly(propylene ether) glycol sold under the tradename NIAX by Union Carbide Co. and having a molecular weight of about 2025 was degassed for 2 hours at C and thereafter charged to a resin kettle maintained under a nitrogen atmosphere and equipped with a condenser, stirrer, thermometer and gas inlet and outlet. 118 g. (0.68 moles) of tolylene 2,4-diisocyanate was charged to the kettle and the reaction was heated with stirring for 2 %hours at 120 C. After cooling, 58 g. (1.0 moles) of allyl alcohol was added to the kettle and the mixture was refluxed at 120 C for 16 hours under nitrogen. Excess allyl alcohol was removed overnight by vacuum at 100 C. Half of the allyl terminated liquidprepolymer having a viscosity of 19,400 cps at 30 C as measured on a Brookfield Viscometer was removed from the kettle and will be referred to hereinafter as Prepolymer G. The other half portion of the prepolymer was combined with 50 cc. of dry benzene and azeotroped overnight following which excess benzene was pulled out under vacuum for 5 hours at 120 C. This portion of the allyl-terminated liquid prepolymer had a viscosity of 15,600cps at 70 C as measured on a Brookfleld Viscometer and a molecular weight of approximately 2500 and will hereinafter be referred to as Prepolymer H.

EXAMPLE 8 751 g. (0.38 moles) of a commercially available poly(propylene ether) glycol sold under the tradename Pluracol P 2010 by Wyandotte Chemical Co. was degassed at room temperature for 3 hours and then charged to a dry resin kettle maintained under a nitrogen atmosphere and equipped with a condenser, stirrer, thermometer and gas inlet and outlet. 132 g. (0.76 moles) of tolylene-2,4-diisocyanate was charged to the kettle and the kettle was heated for 2 hours at 120 C with stirring under nitrogen. After cooling 58 g.

(1.0 moles) of allyl alcohol was added and the mixture.

was refluxed at 120C overnight. Excess allyl alcohol was stripped by vacuum overnight at 120 C. The thus formed allyl terminated liquid prepolymer had a viscosity of 15,000 cps as measured on a Brookfield Viscometer at 70C and a molecular weight of approximately 2500 and will hereinafter be referred to as Prepolymer 1.

EXAMPLE 9 To a 1 liter resin kettle equipped with stirrer, thermometer, gas inlet and outlet and heated to a temperature of 50C was charged 610 g. (0.2 mole) of The temperature of the kettle was raised to C and the contents were freed of water under 1 millimeter vacuum for 1 hour. The resin kettle was cooled to 60 C and the system was placed under a protective atmosphere of nitrogen throughout the remainder of the reaction. 25.2 .g. of allyl isocyanate, (0.4 mole) was added dropwise tothe kettle at such a rate as to maintain the temperature at 60 C. When the NCO content dropped to 0.54 mg/g., 1 mm. vacuum again was applied and the system was heated at 70 C for 1 hour. The thus formed polymer product was a solid at room temperature but at 50 C is clear and pourable. The polymer product had a viscosity .of 1,800 centipoises at 70 C as measured on a Brookfield Viscometer and an average molecular weight of approximately 3,200.

EXAMPLE To a 1 liter resin kettle equipped with stirrer, thermometer, gas inlet and outlet was charged 591 g. (0.30 mole) of a poly(propylene ether) glycol commercially available from Union Carbide under the tradename PPG 2025 and:0.3 g. of dibutyl tin dilaurate. The kettle was heated to 1 10 C and the contents were freed of water under 1 mm. vacuum for 1 hour. The kettle was-cooled to 25 C and they system was placed under a protective atmosphere of nitrogen throughout the remainder of the reaction. 53.1 ml. (493 g., 0.6 mole) of allyl isocyanate. commercially available from Chemetron Corp. was added to the system. An exotherm carried the temperature to 45C in 22 minutes. After 60 minutes, the NCO content (as determined by titration) was 0.04 mg/g. The system was placed under 1 mm. vacuum andheated to 70 C to remove traces of unreacted allyl. isocyanate. The resultant polymer product had a viscosity of 600 centipoises at 30 C as measured on a Brookfield Viscometer and an average molecular weight of approximately 2,200.

The next two examples show a method of preparing the polyenes of the instant invention by dehydration of polyether glycols.

EXAMPLE 1 l 100 g. of poly (propylene ether) glycol commercially available from Union Carbide under the tradename PPG '2025 was poured througha hot tube filled with aluminum oxide at such a rate that the entire reaction took plage in 2 hours. The tube was 1 inch in diameter with thiaien "z'hifi. 1011 358 completely enclosed within a tube furnace. The alumina catalyst was 10-18 mesh and was maintained at 350 C using a Lindberg l-levi-Duty tube furnace. The

tube was fitted with a dropping funnel and a nitrogen EXAMPLE 12 l kilogram of poly(propylene ether) glycol commercially available from Union Carbide 1 under the tradename PPG 2025 was heated to 120 C in a round bottom flask. To this was added 120 ml. (20 per- 16 cent excess) of acetic anhydride at such a rate that the temperature of the mixture was kept at l20- 140C. Following the addition, the mixture was heated at 140 C for 4 hours. It was then cooled and diluted with an equal volume of chloroform, washed with 10 percent aqueous sodium carbonate, then with water. The-"organic layer was separated and the chloroform was removed by distillation. Infrared analysis of the purified material showed it to be the diacetate of the poly(propylene ether) glycol with no residual hydroxyl groups. a r

100 g. of this diacetate was put through the hot tube as in Example 1 1 except that the packing was glass helices instead of alumina and the temperature was 375 C. The product contained 64 percent of the theoretical amountof unsaturation expected after the elimination of acetic acid fromboth terminal acetoxy groups. of the poly (propylene ether) glycol diacetate.

EXAMPLE 13 114 g. of hexol sold under the tradename NlAX Polyol LS-490 by Union Carbide Chemicals Co. having a molecular weight of 684 was charged to a 1 liter 4' neck flask and heated to 110 C under vacuum and nitrogen for 1 hour. It was then cooled to approximately 60C whereat 0.1 cc. of dibutyl tin dilaurate was added followed by slowly adding 83 g. (1 mole) of allyl isocyanate to keep the temperature in the range C during the addition. After addition, the reaction was allowed to continue for 1 hour at 70 C. The polymeric hexaene product obtained had an average molecular weight of approximately 1,200 and a viscosity of 300 centipoises at 70 c.

EXAMPLE 14 obtained had an average molecular weight of approximately 2,100.

EXAMPLE 15 To a 1 liter 4 neck flask was charged cc. of dimethylformamide, 100 g. of tolylene-2,4-diiso-. cyanate and 0.1 cc. dibutyl tin dilaurate. 5 8 g. of hexol, i.e. NlAX Polyol LS-490" by Union Carbide and 34 g. of allyl alcohol were mixed togetherand added dropwise to the flask. Before the addition to the flask was completed, the reaction, whichwas exothermic, gelled and the addition was discontinued.

A comparison of Examples l3, l4 and 15 shows that Example 13 is an improvement over Examples 14 and 15 in that it allows one to form polymer without the necessity of a solvent. A comparison of Examples 14 and 15 shows that when starting with a highly functional polyol using the diisocyanate/allyl alcohol technique one must operate in dilute solution to avoid premature crosslinking (i.e. gelation) which renders the polyene product useless as a curable liquid prepolymer. This problem is avoided completely by using the unsaturated monoisocyanate technique illustrated in Example 13.

EXAMPLE l6 In a 1 liter 4 neck flask 220 g. of hexol commercially available from Union Carbide Chemicals Co. under the tradename NlAX Polyol LS-490 (0.32 moles) and 0.1 cc. of dibutyl tin dilaurate was heated to 100 C under vacuum for 1 hour. After cooling in nitrogen to approximately 60 C, 80 g. of allyl isocyanate was added to the flask by means of a dropping funnel. The exothermic'reaction produced a temperature of 100 18 EXAMPLE 18 To a 1 liter 4 neck flask heated at 110 C was charged 808 g. of a polyester diol (having a molecular weight 3232) sold under the tradename RC Polyester 8 101-35 by R. C. Division Hooker Chemical Corp. and 0.1 cc. dibutyl tin dilaurate. The flask was maintained under vacuum at 110 C for 1 hour. The flask was cooled to approximately 50 C and with nitrogen passing through, a mixture of 10 g. of allyl alcohol and 60 g. of tolylene-2,4-diisocyanate was added via a dropping funnel at a moderate rate. The reaction was allowed to continue for minutes. A maximum'temperature of 90 C was produced by the exothermic C. When the addition was complete the reaction was reaction. The polymeric product obtained was a solid continued at 70 C for 1 hour. The resulting triene polymer product had an average molecular weight of approximately 950 and a viscosity of 300 centipoises as measured on a Brookfield Viscometer at 70 C.

EXAMPLE 17 To a 1 liter 4 neck flask was charged 300 g. of a polyester diol (molecular weight 3232) sold under the tradename RC Polyester S 101-35 by R. C. Division,

Hooker Chemical Corp. and 0.1 cc. of dibutyl tin dilau- O HCEC-C Ha-O-l-NH was added by means of a dropping funnel to the reaction at a moderate rate. A maximum'temperature of 90 C was needed. When the addition was complete the reaction was allowed to continue at 70 C for 1 hour. The thus formed solid polymeric product had an average molecular weight of approximately 6,800 and a at room temperature but liquid at 70 C. The product had an average molecular weight of approximately 10,500 and a viscosity of 270,001 centipoises at 70 C.

EXAMPLE 19 Following the procedure of Example 12 and using necessary reactants, a polyene of the following formula was prepared: 4

gm q auro) EXAMPLE 20 Following the procedure of Example 3, and using necessary reactants, a polyene of the following formula 0 was prepared:

CH3 CH EXAMPLE 21 A crotyl-terminated polyurethane which contains two reactive double bonds per average molecule in a near terminal position was prepared following the general procedure of Example 3. The resulting viscosity of 13,600 centipoises when measured on a polymeric polyene was found to have the following for- Brookfield Viscometer at 70 C.

mula:

9. EXAMPLE 22 Following the procedure of Example 3, and using necessary reactants, a polyene of the following formula was prepared: I

EXAMPLE-23 Following the procedure of Example 3, and using necessary reactants, a polyene of the following formulaf was prepared: l

EXAMPLES 24-42 Following the general procedure of the prior examples, and using the necessary reactants, a series of polyenes having the formula Component [B] CH: N C 0 Ex. No. Component [A] NCO Dibromoneopentyl glycol, DOW SA-1138,

3 moles.

NCO 'Dibromonoopentyl glycol, DOW SA-1138,

6 moles.

2,6-/2,4-toly1ene diisocyanate blend, 4 moles.

2,6-/2,4-tolyieno diisocyanate blend, 6 moles.

Component [X] 2-ch1oro-2propeno1-1, 2 moles.

2-vlnyloxyethanol, 2 moles.

EXAMPLE 43 EXAMPLE 44 0.005 mole of the allyl-terminated liquid Prepolymer A was charged to a 2 oz. glass jar along with a stoichiometric amount of a polythiol to react with the Cl-l =Cl-l groups of the polyene, i.e., 0.0025 mole of pentaerythritol tetrakis (thioglycolate) having a molecular weight of 432. The liquid reactants were mixed together and stirred frequently while heating for one-half hour at 130 C. Thereafter the reactants were left indoors under ambient conditions at atmospheric pressure. At the end of a one week period, a solid, odorless, elastomeric, cured polythioether polymer resulted.

EXAMPLE 45 Example 44 was repeated except that 0.0025 mole of pentaerythritol tetrakis(B-mercaptopropionate), molecular weight 488, was substituted for the pentaerythritol tetrakis(thioglycolate) in Example 44 After a 1 week period, a solid, odorless, elastomeric, cured polythioether polymer resulted.

EXAMPLE 46 Example 44 was repeated except that 0.0033 mole of trimethylolpropane' tris(B-mercaptopropionate having a molecular weight of 398 was substituted for the pentaerythritol tetrakis(thioglycolate). Thereaction mixture began curing when taken from the oven and a solid, odorless, self-supporting, cured elastomeric polythioether polymer resulted after 1 1% days.

EXAMPLE 47 0.005 mole of the allyl-terminated liquid Prepolymer E was charged to a 2 02. glass jar along with a stoichiometric amount of a polythiol to react with the allyl groups in Prepolymer E, 0.0036 mole of trimethylolpropane tris(B-mercaptopropionate). The

liquid reactants were stirred together briefly at room temperature and allowed to stand under ambient conditions. After 8 hours a solid, odorless, self-supporting, cured elastomeric polythioether polymer resulted EXAMPLE 48 Example 47 was repeated except that 0.0027 mole of pentaerythritol tetrakis(B-mercaptopropionate) was substituted for the trimethylolpropane tris(B-mercaptopropionate) and the reactants were stirred for onehalf hour at 130 C before curing under ambient condi- 26 tions. After '4 hours a cured solid, odorless, self-su porting, elastomeric polythioether polymer resulted.

EXAMPLE 49 0.005 mole of the HC cterminated liquid Prepolymer B was charged to a 2 oz. glass jar along with a stoichiometric amount to reactwith the HC i C- groups in Prepolymer B of trimethylolpropane tris(#mercaptopropionate) (0.0033 mole). The reactants were stirred together and stirred-for 4 hours at C. After a 2 week period a cured, solid, odorless, self-supporting, elastomeric polythioether polymer resulted.

' I EXAMPLE 50 0.005 mole of the allyl-terminated liquid Prepolymer F was charged to a 2 oz. glass jar alongwith a stoichiometric amount to react with the allyl groups of the Prepolymer, i.e., 0.0033 mole of trimethylolpropane tris(B-mercaptopropionate) having a'molecular weight of 398. The liquid reactants were stirred together for one-half hour at C. Thereafter the reactants were cured under ambient conditions. After 2 A days the liquid reactants began curing and at the end of a 2 week period, a solid, odorless, self-supporting, cured elastomeric polythioether polymer resulted.

The following examples show the curing reaction of the instant invention as catalyzed by a peroxide. In all the examples 10 g. of the allyl-terminated liquid polyene prepolymer were admixed in a 2 02. glass jar with a stoichiometric'arnount of a polythiol, i.e. pentaerythriol tetrakis (B-mercaptopropionate) sufficient to react with all the allyl groups on the prepolymer. In addition, the peroxide was added along with an accelerator for the peroxide. The reactants were briefly 4 stirred and then left to cure indoors at ambient conditions. The results follow: I

The following examples 54-59 show curing of filled I compositions when catalyzed by oxygen. In all examples, 10 g. of the allyl-terminated liquid prepolymer were charged to a 2 02. glass jar along with a stoichiometric amount of a polythiol curing agent, i.e. pentaerythritol tetrakis (B-mercaptopropionate) and a filler. The mixture was stirred briefly and then cured under ambient conditions. A comparison of Examples 57 and 58 shows the necessity of having a polythiol present to obtain a cured solid polymer.

Polythiol Pre ex. polyno. .mer

Curing Observations A Cured toan odorless solid in 4 hrs. Cured to an odorless solid in 4 hrs.

54 l 8.0 g. Emtal 'Ialc 55 l 8.0 g. Unimal 303 A 56 l 8.0 g. Desertalc 132 Cured to an odorless I solid in 24 hrs. I Cured to an odorless solid in l I: hr. No cure after 30 days Cured to an odorless solid in 4 hrs.

57 l 3.0 g. l-liSil 233 58 1 3.0g. HiSi1233 None 59 3.0 g. l-liSil+5gTio,

( l A pentaerythritol tetrakis (B-mercaptopropionate) (2) A talc commercially available from Eastern Magnesia Talc Co., Burlington, Vt.

(3) Polyaluminum silicate manufactured by United Clay Mines, Trenton, N. J.

(4) An acicular platey talc commercially available from Desert Minerals lnc;, Los Angeles, Calif.

(5) A -reiniorcing silica commercially available from Columbia Southern Chemical Corp., Pittsburgh, Pa.

The following examples show the operability of various liquid polyene andpolythiol systems to form cured solid polymers by the process of the instant invention.

EXAMPLE 60 with stirring under nitrogen. Thereafter, 116.9 g. (2

moles) of allyl alcohol was added to the kettle and the mixture was refluxed for 16 hours at 120 C. Excess allyl alcohol was stripped by vacuum at 115 C for 23 hours. The thus-formed Cl-l,=CH- terminated polyene prepolymer had a molecular weight of approximately 2,4602,500, and a viscosity of 16,000 cps as measured ona Brookfield viscometer at 30 C.

0.005 mole of the thus-formed polyene and 0.005 mole of trimethylolpropane triallyl ether were charged to a 2 oz. glass jar along with a stoichiometric amount of the polymeric dithiol prepared in Example 66. After adding 0.063 gram of benzoyl peroxide and 0.15 gram of dimethylaniline, the mixture in the glass jar was immediately stirred.- Thereafter the mixture was poured intoa plastic mold for curing. Within 30 minutes a solid, self-supporting, odorless, cured elastic polymer resulted.

to a 2 oz. glass bottle along with a stoichiometric amount of a polythiol to react with the-CH,=CH- groups in the diallyl adipate, i.e., 4.9g. (0.01 mole) of pentaerythritol tetrakis(B-mercaptopropionate), 0.05 g. of lauroyl peroxide and 0.15 gQdimethylaniline. The reactants were stirred briefly and then placed on the bench top at ambient conditions. A self-supporting, solid, odorless, cured polythioether polymer resulted in less than 15 minutes.

EXAMPLE 62 Example 61 was repeated except that 0.02 mole of diallyl phthalate was substituted for the diallyl adipa te. A self-supporting, solid, odorless, cured polythioether polymer product resulted in less than 30 minutes.

EXAMPLE 63 Example 61 was repeated except that 0.02 moleof diallyl succinate was substituted for the diallyl adipate. A self-supporting, solid, odorless, cured polythioether product resulted in 30 minutes.

EXAMPLE 64 Example 61 was repeated except that 0.02 mole of 2,2-diallyloxypropane was substitutedfor the diallyl adipate. A self-supporting, solid, odorless, cured polythioether polymer product resulted in less than 15 minutes.

EXAMPLE 65.

1.9 grams (0.02 mole) of diallyl amine were charged to a 2 oz. glass bottle along with a stoichiometric amount of polythiol to react with the vinyl groups in the 5 diallyl amine, i.e., 4.9 g. (0.01 mole) of pentaerythritol tetrakis(fi-mercaptopropionate), 0.04 g. benzoyl peroxide and 0.1 g. dimethylaniline. The reactantswere stirred briefly. In less than 15 minutes a self-supporting, solid, odorless, cured, clear, rubbery 40 polythioether polymer resulted.

The following shows another example of the curing of a polymeric thiol-containing compound and a vinylterminated polymer.

EXAMPLE 66 1.5 moles of B-mercaptopropionic acid, 0.5 mole of a commercially available poly(propylene ether) glycol sold under, the tradename Pluracol P-20l0by Wyandotte Chemical Corp. and 0.1 g. p-toluenesulfonic acid and 50 ml. benzene were charged to a resin kettle maintained under a nitrogen atmosphere and equipped with a condenser, stirrer, thermometer and gas inlet and outlet. The mixture was heated and the benzenewater azeotrope was collected. The actual amount of water collected amounted to 17.5 g. The reaction was vacuum-stripped for several hours at 70 C to remove benzene. The resulting polythiol polymer had a molecular weight of about 2,210-2,230 and an average functionality of 2 and was collected for use herein.

659 g. (0.145 mole) of a poly(propylene ether) triol commercially available from Wyandotte Chemical Corp.'under the tradename Pluracol TPE 4542having a molecular weight of about 4,500 and a hydroxyl number of 37.1, and 0.3 g. of dibutyl tin dilaurate were charged to a resin kettle maintained under a nitrogen atmosphere and equipped with a condenser, stirrer,

were maintained at C for 1 hour and then cooled under nitrogen to room temperature. 25.2 g. (0.435 mole) of allyl alcohol was added to the kettle followed by 75.7 g. (0.435 mole) of an 80-20 percent isomer mixture of tolylene-2,4-diisocyante and tolylene 2,6- diisocyanate respectively sold under the .tradename Mondur TD 80". The temperature reached 55 C in 6 minutes. A sample was titrated for NCO resulting in 6.02 mg. NCO/g. after 20 minutes. After 1 hour the NCO titration showed 0.997 mg. NCO/g. The polyene polymer had a molecular weight of about 5,200 and an average functionality of 3 and was vacuum stripped at 70 C for 1 hour and then collected. 0.003 mole of the polythiol polymeric material formed supra was charged to a 2 oz. glass jar along with 0.002 mole of the allylterminated polyene polymer formed herein, 0.10 g. benzoyl peroxide and 0.20 g. dimethylaniline. The reactants were stirred briefly. In less than one-half hour a self-supporting, solid, odorless, clear, cured polythioether polymer product resulted.

EXAMPLE 67 3 grams of a linear saturated hydrocarbon backbone ethylene/propylene/nonconjugated diene terpolymer commercially available under the trade name Nordel by E. I. duPont de Nemours & Co., which has been visbroken until it had a reduced specific viscosity of 0.99 and contained 0.4 vinyl, 6.4 trans and 0.4 vinylidene unsaturated groups per 1,000 carbon atoms, were dissolved in 100 ml. of benzene in a glass jar. A 50 percent excess over the stoichiometric amount, i.e., 0.0006 mole (0.3 g.) of pentaerythritol tetrakis(fi-mercaptopropionate) was added to the jar in addition to 0.015 g. benzoyl peroxide and 0.03 g. dimethylaniline. The glass jar was set aside under ambient conditions. After 24 hours the benzene had substantially evaporated leaving a gelatinous polymeric precipitate. Acetone was added to precipitate more polymer. The polymer was filtered off, washed with acetone and dried in a vacuum oven at 60 C.

2.3 grams of the above polythioether polymer product was extracted with benzene along with a con trol sample of the starting visbroken Nordel material. The control sample showed a nil gel content (benzene insoluble) whereas the peroxide cured (crosslinked) solid polythioether polymer product ha a gel content in excess of 50 percent.

EXAMPLE 68 643 grams (0.32 mole) of a commercially available poly(propylene ether) glycol sold under the trade name Pluracol P 2010by Wyandotte Chemical Co. were degassed at room temperature for 1 hour and then charged to a resin kettle maintained under a nitrogen atmosphere and equipped with a condenser, stirrer, thermometer and gas inlet and outlet. 111.4 grams (0.64 mole) of an 80-20 percent isomer mixture of tolylene-2,4-diisocyanate and tolylene-2,6-diisocyanate, respectively, sold under the trade name Mondur TD 80, were added to the kettle. After 45 minutes, the temperature was raised to 120 C and the reaction was continued for 50 minutes. A sample was removed and titrated for NCO, resulting in 33.54 mg.

NCO/g. 62.7 grams of diallyl amine were added at 105 C and the reaction was continued for minutes. A sample was titrated resulting in an NCO content of 1.20 mg. NCO/g. A vacuum was applied to the kettle for 1 hour at 90C followed by cooling under nitrogenjlfhe resulting product had a molecular weight of about 2,5 40-2 ,5 80 and an ene functionality of 4.

10 grams of the thus-formed'polymer were charged to a 2 oz. glass jar along with 2 g. of pentaerythritol tetrakis(}3- mercaptopropionate) and 0.06 g. azobisisovaleronitrile. The liquid reactants were briefly stirred together and set aside under ambient conditions. Within 30 minutes a solid, odorless, elastomeric, cured polythioether product was obtained.

EXAMPLE 69 215 grams of poly(ethylene imine) commercially available from Dow Chemical Co. under the trade name Montrek 18 along with 41.5 g. allyl isocyanate were chargedto a resin kettle maintained under a nitrogen atmosphere and equippedwith a condenser, stirrer, thermometer and gas inlet and outlet. The reactants were maintained at 70 to C during addition. The reaction was continued for 1 hour at 70 C.

10 grams of the thus-formed polymer were charged to a 2 oz. glass jar along with 1.5 g. of pentaerythritol tetrakisUB-mercaptopropionate) and 0.25 g. of azobisisobutyronitrile. The mixture was briefly stirred and placed in a warm room at about 120 F. Within 2 hours a solid, self-supporting, odorless, cured polymer product was formed.

EXAMPLE 70 EXAMPLE 71 400 grams (0.20 mole) of a commercially available liquid polymeric diisocyanate sold under the trade name Adiprene L by E. l. duPone de Nemours & Co. were charged to a dry resin kettle maintained under a nitrogen atmosphere and equipped with a condenser, stirrer, thermometer and gas inlet and outlet. 25.2 grams (0.45 mole) of propargyl alcohol were charged to the kettle and the reaction was continued for 17 hours with stirring at 100 C. Thereafter the nitrogen atmosphere was removed and the kettle was evacuated 15 hours at 100 C.

10 grams of the propargyl terminated liquid prepolymer, 3.0 grams of pentaerythritol tetrakis(flmercaptopropionate), 0.06 gram of benzoyl peroxide and 0.15 gram of dimethylaniline were admixed in a 2 oz. glass jar, stirred briefly and set aside under ambient conditions. Within one-half hour a solid, odorless, selfsupporting, cured, elastomeric polymer product resulted.

The following example shows the necessity of having a free radical generator present, e.g., oxygen, in order to cure by the instant invention.

EXAMPLE 72 40 grams of Prepolymer l and 10 grams of a filler sold commercially under the trade name Hi Sil 233 by Columbia Southern Chemical Corp. were charged EXAMPLE l25 g. of Prepolymer E from Example 5 herein was charged to a Erlenmeyer flask equipped with a magnetic stirrer and connected by tubing to another Erlenmeyer flask containing 54 g. of trimethylolpropane tris (B-mercaptopropionate). The system was evacuated (0.05 mm.) while heating the polymer to 100 C with stirring. After 2 .hours all bubbling ceased. An additional one-half hour evacuation was performed.

Thereafter the trimethylolpropane tris(B-mercaptopropionate) was poured into theflask containing Prepolymer E under" nitrogen. After stirring to insure good mixing, heat was removed and the reaction was continued under nitrogen for 4 days. No curing was observed. A sample of the unreacted material was removed from the Erlenmeyer flask under nitrogen and placed in a 2 oz. jar. The sample was exposed to ambient conditions, indoors and in about 40 minutes evidence of curing (viscosity change) was observed. Within 8 hours, an odorless, solid, elastomeric, cured polymer product was obtained.

The following example shows the ability to retard the curing process of the instant invention by the use of anti-oxidants.

each of three 2 oz. jars. To one of the jars was added 3 ml. of benzene containing 0.5 percent based on the weight of the prepolymer of an antioxidant sold under the tradename .Santonox commercially available from Monsanto Chemical Co. To another of the jars containing Prepolymer E was added 3 ml. of benzene containing 0.5 percent based on the weight of the prepolymer of an antioxidant sold under'the tradename Dalpac FG commercially available from Hercules Powder Co. To the third jar was added 3 ml. of benzene as a control. To blend the components the jars were heated in a forced draft oven set at 150 C for 25 minutes with frequent stirring. The jars were withdrawn from .the'oven and 1.3 g. of trimethylolpropane tris (B- mercaptopropionate) was added to each of the jars and curing was initiated indoors under ambient conditions.

The control run, without any 'ariti oxidant present, cured within l/2 hour to a solid elastomeric polymer product. The example containing Dalpac FG cured to a solid polymer product after 12 days whereas the samplecontaining Santonox required more than 2 weeks before a solid self-supporting, cured polymeric product resulted.

The polyenes used in the instant invention may be used as blends or mixtures of monoenes or polyenes having the same or different functionalities so long as the. average functionality of the blend or mixture is at least 2. Similarly, the polythiols usedherein may be used as blends or mixtures of monothiols or polythiols having the same or different functionalities as long as the average functionality of the blend or mixture is at least 2..

The polyene/polythiol mole ratio is selected so as to' provide a solid final cured'product, i.e., one that is nonflowing and structurally self-supporting under ambient conditions. In typical .cases, as shown by the. examples, this ratio can be about 0.2 to 5 moles thiol groups per mole ene groups. In general the mole ratios significantly above or below i tend to give a high proportion of chain extension or grafting whereas mole ratios near 1 give predominantly chain extension and crosslinking. Occasionally, however, ratios necessary to give a solid as aforesaid may lie outside the stated range, and experimentation may be necessary to determine a suitable ratio to give a solid. This experimentation is easily carried out, and offers no difficulties to those skilled in the art. Examples 75-80 and 81-86 show how to vary the ratio and how one can. empirically determine the amount of polythiol necessary to react with the polyene to obtain a solid, self-supporting, cured polymeric product. I

Examples 75-80 show the ability to use mixtures of the polythiols and how to empirically determine the amount of polythiol necessary to form cured, solid, self-supporting polymeric products by the instant invention.

As shown in Examples 75-80, 30 grams of Prepolymer I from Example 8 were admixed with varying ratios of a mixture of polythiols and cured in the presence of a peroxide with dimethylaniline as a peroxide activator.

ln examples 8l-86,'30 grams of Prepolymer i from Example 8 were admixed with varying amounts ofa polythiol, i.e., pentaerythritol tetrakis (IS-inercaptopropionate) along with 1.5 g. of i0 percentbenzoyl' peroxide (in benzene) and 0.3 g. of dimethylaniline. The mixture was briefly stirred in a 2 oz. glass jar and then transferred to a shallow aluminum foil dish. The mixtures were then allowed to cure indoors under ambient conditions. The results of the amount of reactants nrecessary for a self-supporting polymeric structure are s own..

EXAMPLES 75-80 10% solution Polythiol mixture in benzene of benzoyl Dimethyl Curlng Seli- Polyene Q43 2 E-23 3 peroxide aniline time Shore A supporting Example No polymer 1 (g.) (g.) (g.) (min.) hardness structure 2. 9 0 1. 5 0.3 3 23 Yes. 2. 3 0. 6 1. 5 0. 3 6 13 Yes. 1. 7 1. 2 l. 5 0. 3 7 0 Yes. 1.2 1.7 1.5 0.3 9 0 Yes.. 0.6 2.3 1.5 0.3 No. 0 2.9 1.5 0.3 No.

l PolycnePrepolymer I from Example 8. 2 Q43=Pentaerythritoi tetrakis (B mercaptopropionate) commercially available from Carlisle Chemical Co. 8 E23=Ethylene glycol bis B-mercaptopropionate).

t No cure.

EXAMPLES 81-86 Product properties 10% benzoyl Dlmethyl Self- Polyene Polythiol peroxide aniline Shore A supporting Example N o. polymer 1 (1-43 2 (g.) (g.) (g.) Curing time hardness structure I 1. 7 1. 5 I 1. 5 1. 5 I 1. 2 1. 5 I 0.0 1.5 I 0. 6 1. 5 I 0. 3 l. 5

l 30g. Polyene prepolymer I from Example 8.

2 Q43=pentaerythrltol tetrakis (fl-mereaptopropionate) commercially available from Carlisle Chemical Co.

EXAMPLE 87 The following formulations were made up:

Ingredients Formulation Formulation No. I No. II (Parts) (Parts Prepolymer D from Example 4 I 100 TiO, (pigment) 4 4 Unimal 507 (kaolin clay) 60 85 Unirnal 303 (kaolin clay) 25 0 Thickening agent (75% silica gel- 25% asbestos fibers) 4 4 Pentaerythritol tetraltis (flmercapto-propionatc) l0 10 The above formulations were briefly admixed for homogeneity and thereafter air cured indoors. Formulation I cured in approximately 6 hours to an elastomeric sealant whereas Formulation ll cured in 2 days to an elastomeric sealant.

EXAM PLE 8 8 EXAMPLE 89 50 grams of Prepolymer H along with 5.0 g. of pentaerythritol tetrakis(B-mercaptopropionate), 2.5 g. of a 10 percent benzoyl peroxide in benzene and 0.5 g. N,N-dimethylaniline were stirred together briefly in a glass jar and then poured into an aluminum mold in the shape of a shallow dish. The mold was allowed to set for hours after which time the mold was torn away from the molded article which set to a solid in the exact shape of the mold.

EXAMPLE 90 0.005 mole of Prepolymer E from Example 5 was charged to a 2 oz. glass jar along with 0.0033 mole of trimethylolpropane tris(B-mercaptopropionate), 0.2 g. benzoyl peroxide and 0.5 g. dimethylaniline. The reactants were stirred briefly and then coated onto a piece of 17 pt. clay coated paper by means of a No. rod. The paper was then set aside at ambient conditions.

After 10 minutes a clear, solid coating resulted on the paper. The same technique was used successfully to coat cellophane, aluminum foil, steel plate stock, Mylar polyester film, plywood, and a concrete block of the type usedin building construction.

EXAMPLE 91 20 grams of the polymeric product from Example 10 was mixed in an aluminum dish with 2.2 g. of pentaerythritol tetrakis(B-mercaptopropionate) commercially available from Carlisle Chemical Co. under the tradename Q-43, 0.10 g. benzoyl peroxide and 0.2 g. dimethylaniline. The sample cured to a tack-free solid which had a color of less than 1 on the Gardner Scale. After exposure in a Fadeometer for 50 hours, the color increased to a value of 4 on the Gardner Scale.

A similar polymer prepared from FPO-2025," tolylene-Z,4-diisocyanate and allyl alcohol, cured with pentaeryth-ritol tetrakis(B-mercaptopropionate) and acetophenone by irradiation with ultraviolet light also had a Gardner color of less than 1. However, after 50 hours in the Fadeometer the Gardner color rose to l 3.

EXAMPLE 92 5.2 grams of decaglycerol dioleate (Drew Chemical Corp.) and 2.0 grams of ethylene glycol bis(B-mercap- EXAMPLE 93 94.5 grams of dimer acid commercially available from Emery Industries, Inc., under the trade name Empol 1010 and 103.5 grams of allyl alcohol were admixed in benzene in a two-neck flask. The reaction was heated gently for 19 hours at C at which time it was determined by titration that less than 6 percent of the carboxyl group content was unreacted. The reaction was discontinued and the reactants were washed with water. The thus-formed emulsion was salted out thoroughly, the benzene layer was separated and dried to remove residual moisture. The benzene was distilled off in vacuum to obtain the diallyl ester of dimer acid.

The diallyl ester of the dimer acid product (30 grams) was admixed with Q-43 in a 1:1 mole ratio along with 0.15 gram benzoyl peroxide and 0.3 gram dimethylaniline in an aluminum tray. After 30 minutes a cured solid product resulted.

The curing example was repeated except that the mole ratio of the diallyl ester of dimer acid to Q43 was 2:1. The cured product was harder than the product obtained under the 1:1 mole ratio of diallyl wooeoi,

.215. 36 14 grams of dimer acid, 6 grams of pentaerythritol the similar synthesis described in Example 116. The tetrakis(B-mercaptopropionate), 0.07 gram benzoyl resulting diene (3 moles) was mixed with 21 moles of peroxide and 0.l5 gram dimethylaniline were mixed in the tris( 3-mercaptopropyl) ether of tris( Z-hydroxan aluminum tray. The mixture was set aside under amyethyl).isocyanurate, 0.5 part benzoyl peroxide and 1.0

bient conditions. After 22 hours the product had not 5 part dimethylaniline per 100 parts of curable composisolidified to a cro s l inlgednetworlg. tion. I

EXAMPLES 94-111 Chemical free radical Sample No. Polyene Source of polyene generating reagent 1 Polythlol 2 M 1,2,4-trlviny1cyclohexanc Aldrich Chemical 00., Inc Benzoyl peroxide Q43 96 1,5-hexadiene do Q43 96. Diallyl terephthalate Chemicals Procurement Lab. Inc Q-43 97- Dlallyl oxalate Monomer-Polymer Labs, Inc. Q-43 98. Diallyl1,4-cyclohexane-dicarboxylat do Q43 99- Tetraallyl orthosllic e Aldrich Chemical 00., Inc Q43 100--. Diallyl diphenglsilane Chemicals Procurement Lab., Inc do... Q43 101 Dlallyl allyl p osphonate Aldrich Chemical 00., Inc do... Q43 102 Diallyl phenyl phosphite K. 6: K. Laboratories, Inc.. do. Q-43 N,N-diall lormamide Aldrich Chemical Co.,Inc. do. Q43 ,N N ,N-tetraallyl-methylenediamin Monomer-Polymer Labs, I do- (.1-43 Trlal'lylcyanurate Aldrich Chemical 00., Incdor-sa 4-viny1-1-cyclohexene K. & K. Laboratories, Inc-. .do. Q43

Dlethyleneglycol divinyl ether (.9 mole) Polysciences, Inc do Q43 Diallyl amine (.1 mole); Monomer-Polymer Labs., Inc...

. Aldrich Chemical Co. Inc

Chemicals Procurement Lab. Inc

1 Concentration of dimethylaniline curing rate accelerator varied from 1.0 to 3.0 parts/100 parts curable composition; benzoyl peroxide reagent concentration was 0.2 to 0.5 part/100 parts of curable composition. Cure through times ranged from 3 minutes to minutes.

2 Q-43 is pentaerythritol tetraktls (fl-mercaptopropio'nate; P-33 is trimethylelpropane tris (B-mercaptopropionate). The polythiol is used in the theoretical equivalent amount based on the polyene used. v

EXAMPLES ll2-l20 100 grams of the above curable composition were placed in a layer 500 mils deep in a small aluminum mold and set aside at ambient conditions. After 5 minutes the-liquid composition was cured to a crosslinked solid having a Shore A hardness greater than 20. The conversion from liquid to solid occurred at a rate of over 100 mils/minute.

The solid cured polythioether polymer products EXAMPLE I21 35 resulting fromthe instant invention have many and varied uses. Examples of some uses include but are not limited to adhesives; caulks; elastomeric sealants; coatings, encapsulating or potting compounds; liquid castable elastomers; thermoset resins; impregnants for Example 65 was repeated except that the 0.02 mole of of diallyl aminewas replaced by 0.02 mole of the polyenes from Examples 24, 25, 27, 28, 3O, 31, 32, 39 and 40, respectively. In each instance a solid cured product was obtained in less than 20 minutes after mixing wascompleted.

916 grams (0.46 mole) of a commercially available liquid polymeric diisocyanate sold under the trade name Adiprene L-lOO by E. l. duPont de Nemours & Co. were charged to a dry flask maintained under a 40 nitrogen atmosphere and equipped with a condenser, fabric, cloth, fibrous webs and other porous substrates;

stirrer, thermometer and gas inlet and outlet. 197 laminatmg adhesives l coatings; masficsi l grams (0.92 mole) of the diallyl ether of trimethylolcompoundi fiberglass relnforfed composltesl 811mg propane were charged to the vessel along with 0.56 g. Surface fimshmg agents; filletmg compounds; cure dibutyl tin dilaurate catalyst. The flask and contents P gasketing f p i rocket fuel binders; r heated with stirring f 30 minutes at C to foamable thermosetting resins or elastomers; molded yield a polytetraene f ab t 2,400 M w articles such as gaskets, diaphragms, balloons, automo- To the tetraene were added 230 grams penbile taerythritol tetrakis(fl-mercaptopropionate), 1.2 grams The molecular weight of the polyenes of the present dilaurylthionclipropionate, 136 grams f dioctyl 50 invention may be measured .by various conventional phthlate, 1.2 grams Plastanox 2246 (hindered phenol methods, including solution viscosity, osmotic pressure antioxidant sold by American Cyanamid Co.), 6.7 and gel permeation chromatography. Additionally, the grams benzoyl peroxide and 14 grams dimethylaniline. molecular weight may be calculated from the known, An aliquot of this chemically curable liquid composimolecular weight of the reactants.

tion was cast on a glass plate in a layer 40 mils thick. The viscosity of the polyenes and polythiols may be The layer skin cured to a solid through the entire measured on a Brookfield viscometer at 30 or 70 C in thickness .in less than 3 minutes, or at a liquid-to-solid accord with the instructions therefor.

conversion rate of over 13 mils/minute. The solid rub- The components to be cured may be prepared as bery product had a Shore A hardness of 60, a tensile either single-packaged or multi-packaged liquid strength of 150 psi and an elongation at failure of 25 polymer systems which may be cured to solid percent. polythioether elastomers without liberating gaseous byw i products which cause bubbles and voids in the vul- EXAMPLE 122 canizate. Thus, there is provided curable liquid An 80/20 "mixture of tolylene 2,4-diisocyanate and polymer systems composed of polyenes and polythiols tolylene 2,6-diisocyanate (1 mole) was reacted with in which the components individually are storage stable allyl alcohol (2 moles) under the conditions used for and which are not sensitive to or deteriorated by traces of moisture or oxygen containing gas such as may be encountered during normal storage or handling procedures. Solid resinous or elastomeric products may be prepared from flowable liquids in a system in which the rate of curing may be inhibited or retarded by the use of chemical inhibitors, antioxidants, inert atmospheres and the like. The cured product may be characterized as in the thermally and oxidatively stable state since there is no reactive carbon-to-carbon unsaturation in the main backbone chain.

As used herein the term polyene and the term polyne refers to single or complex species of alkenes or alkynes having a multiplicity of terminal reactive carbonto-carbon unsaturated functional groups per average molecule. For example, a diene is a polyene that has two reactive carbon-to-carbon double bonds per average molecule, while a diyne is a polyyne that contains in its structure two reactive carbon-to-carbon triple bonds per average molecule. Combinations of reactive double bonds and reactive triple bonds within the same I molecule are also possible such as for monovinylacetylene which is a polyeneyne under this definition. For purposes of brevity all these classes of compounds are referred to hereafter as polyenes.

In defining the position of the reactive functional carbon-to-carbon unsaturation, the term terminal is intended to mean that functional unsaturation is at an end of the main chain in the molecule; whereas by near terminal is intended to mean that the functional unsaturation is not more than carbon atoms and typically less than eight carbon atoms from an end of the main chain in the molecule. The term pendant means that the reactive carbon-to-carbon unsaturation is located terminal or near-terminal in a branch of the main chain as contrasted to a position at or near the ends of the main chain. For purposes of brevity all of these positions are referred to herein generally as terminal unsaturation.

Functionality as used herein refers to the average number of ene or thiol groups per molecule in the polyene or polythiol, respectively. For example a triene is a polyene with an average of three reactive carbonto-carbon unsaturated groups per molecule and thus has a functionality f of three. A dithiol is a polythiol with an average of two thiol groups per molecule and thus has a functionality f of two.

It is to be understood that the functionality of the polyene and the polythiol component is commonly expressed in whole numbers although in practice the actual functionality may be fractional. For example, a polyene component having a nominal functionality of two (from theoretical considerations alone) may in fact have an effective functionality of somewhat less than two. In an attempted synthesis of a diene from a glycol in which the reaction proceeds to 100 percent of the theoretical value for complete reaction, the functionality (assuming 100 percent pure starting materials) would be 2.0. If however, the reaction were carried to only 90 percent of theory for complete reaction, about 10 percent of the molecules present would have only one ene functional group, and there may be a trace of material that would have no ene functional groups at all. Approximately 90 percent of the molecules, however, would have the desired diene structure and the product as a whole then would have an actual functionality of 1.9. Such a product is useful in the instant invention and is referred to herein as having a functionality of 2.

The term reactive unsaturated carbon-to-carbon groups means groups which will react under proper conditions as set forth herein with thiol groups to yield the thioether linkage fi i j as contrasted to the term unreactive carbon-to-carbon a io whish means...

groups found in aromatic nucleii (cyclic structures exemplified by benzene, pyridine, anthracene, and the like) which do not under the same conditions react with thiols to give thioether linkages.

Highly water-sensitive groups are intended to include, for example, isocyanate, acylhalide such as acylchloride, anhydride and the like which readily react with water, alcohols, ammonia, amines and the like.

Odorless has been used herein to mean the substantial absence of the well-known offensive and sometimes obnoxious odors that are characteristic of hydrogen sulfide and the derivative family of compounds known as mercaptans.

The term non-yellowing means the substantial resistance during prolonged exposure to actinic radiation such as exposure in sunlight, to unsightly or uncontrollable discoloration.

It is understood that the foregoing detailed description is given merely by way of illustration and that many variations may be made therein without departing from the spirit of this invention.

What is claimed is:

1. A chemically curable composition useful for obtaining an essentially odorless, solid polythioether, said curable composition consisting essentially of:

A. a terminally unsaturated polyene component which comprises the formula:

lite).

wherein m is an integer of at least 2; wherein X is where R is a radical selected from the group consisting of hydrogen, fluorine, chlorine, futyl, thienyl, pyridyl,. phenyl and substituted phenyl, benzyl and substituted benzyl, alkyl and substituted alkyl, alkoxy and substituted alkoxy, cycloalkyl and substituted cycloalkyl; said substituents on said substituted members selected from the group consisting of nitro, chloro, fluoro, 

2. The composition of Claim 1 wherein (A) has the formula: wherein a and b are integers greater than 1; R2 is a member of the group consisting of hydrogen and alkyl; R3 is a member of the group consisting of hydrogen, and saturated alkyl; R4 is a divalent derivative of the group consisting of phenyl, benzyl, alkyl, cycloalkyl, substituted phenyl, substituted benzyl, substituted alkyl and substituted cycloalkyl, said alkyl, cycloalkyl and substituents on members substituted being defined as in claim
 1. 3. The composition of claim 1 wherein the mole ratio of ene to thiol is from about 0.5/1 to about 2/1.
 4. The composition of claim 1 wherein the mole ratio of ene to thiol is from about 0.75/1 to about 1.5/1.
 5. The composition of claim 1 wherein the chemical free radical generating reagent is selected from the group consisting of molecular oxygen; organic hydroperoxides and peroxides; blends of organic hydroperoxides and peroxides with tertiary amines; blends of organic hydroperoxides and peroxides with transition metal salts; and blends of organic hydroperoxides and peroxides with tertiary amines and transition metal salts.
 6. A process of forming essentially odorless solid polythioether which comprises I. Admixing: A a terminally unsaturated polyene component which comprises the formula: (A - X)m wherein m is an integer of at least 2; wherein X is where R is a radical selected from the group consisting of hydrogen, fluorine, chlorine, furyl, thienyl, pyridyl, phenyl and substituted phenyl, benzyl and substituted benzyl, alkyl and substituted alkyl, alkoxy and substituted alkoxy, cycloalkyl and substituted cycloalkyl; said substituents on said substituted members selected from the group consisting of nitro, chloro, fluoro, acetoxy, acetamide, phenyl, benzyl, alkyl, alkoxy and cycloalkyl; said alkyl and alkoxy having from one to nine carbon atoms and said cycloalkyl having from three to eight carbon atoms; wherein (A) is free of reactive carbon-to-carbon unsaturation; free of highly water-sensitive members; and is a polyvalent chemically compatible member of the group consisting of carbonate, carboxylate, carbonyl, ether, silane, silicate, phosphonate, phosphite, phosphate, alkyl and substituted alkyl, cycloalkyl and substituted cycloalkyl, aryl and substituted aryl, urethane and substituted urethane, urea and substituted urea, amine and substituted amine, amide and substituted amide, hydroxyl, heterocyclic carbon containing radical, and mixtures thereof; said substituents on said members substituted being defined above, said component having a molecular weight in the range from about 64 to 20,000; and a viscosity in the range from essentially 0 to 20 million centipoises at 70* C; and B. a polythiol component having a molecular weight in the range from about 50 to about 20,000 of the general formula: R8- SH)n wherein R8 is a polyvalent organic moiety free from reactive carbon-to-carbon unsaturation and n is at least 2, the sum of m and n being greater than 4, with the ene/thiol mole ratio being selected so as to provide a cross-linked solid, self-supporting cured product, and C. a chemical free radical generating reagent.
 7. An article comprising the composition of claim 6 as a coating on a substrate.
 8. An article comprising the composition of claim 6 as an adhesive between two substrates.
 9. An article comprising the composition of claim 6 as an elastomeric sealant.
 10. A shaped, molded article cast from the composition of claim
 6. 11. The process of claim 6 wherein the chemical free radical generating reagent is selected from the group consisting of molecular oxygen; organic hydroperoxides and peroxides; blends of organic hydroperoxides and peroxides with tertiary amines; blends of organic hydroperoxides and peroxides with transition metal salts; and blends of organic hydroperoxides and peroxides with tertiary amines and transition metal salts.
 12. The composition of claim 1 wherein the polyene has the formula:
 13. The composition of claim 1 wherein the polyene has the formula: where n is an integer of 0 or greater.
 14. The composition of claim 1 wherein the polyene has the formula: where the sum of x + y + z is at least
 1. 